منابع مشابه
Dynamics of living polymers.
We study theoretically the dynamics of living polymers which can add and subtract monomer units at their live chain ends. The classic example is ionic living polymerization. In equilibrium, a delicate balance is maintained in which each initiated chain has a very small negative average growth rate ("velocity") just sufficient to negate the effect of growth rate fluctuations. This leads to an ex...
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We study trie elfects of threeand fourfold crosslinks on wormlike micelles. This
متن کاملThe ultrasensitivity of living polymers.
Synthetic and biological living polymers are self-assembling chains whose chain length distributions (CLDs) are dynamic. We show these dynamics are ultrasensitive: Even a small perturbation (e.g., temperature jump) nonlinearly distorts the CLD, eliminating or massively augmenting short chains. The origin is fast relaxation of mass variables (mean chain length, monomer concentration) which pertu...
متن کاملStatistical thermodynamics of equilibrium polymers at interfaces.
The behavior of a solution of equilibrium polymers (or living polymers) at an interface is studied, using a Bethe-Guggenheim lattice model for molecules with orientation dependent interactions. The density profile of polymers and the chain length distribution are calculated. For equilibrium polymers at a nonadsorbing surface it is found that the depletion layer thickness has a maximum. In dilut...
متن کاملAdsorbed and Grafted Polymers at Equilibrium
This chapter deals with various aspects related to the adsorption of long chain-like macromolecules (polymers) onto solid surfaces. Physical aspects of the adsorption mechanism are elaborated mainly at thermodynamical equilibrium. The basic features needed in modeling of this adsorption are discussed. Among other aspects, we address the type of polymer/surface interaction, the solvent quality, ...
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ژورنال
عنوان ژورنال: Entropy
سال: 2020
ISSN: 1099-4300
DOI: 10.3390/e22101130